Polymer physics is highly useful for understanding many scientific and technological problems associated with the use of such materials in modern engineering and technology. Polymers, defined as non-metallic materials, which can be moulded to any shape and size by application of heat and pressure, have become substance of immense importance. Now a days, the polymers are widely used in the construction, transportation, communication, electrical and textile industries and are highly useful in the aircraft, aerospace, nuclear and space technology as well as medical applications. The Morphological, Structural, Mechanical and Electrical properties of isomorphic polyblends of fluro polymer (PVF: PVDF) were explore in this book. Moreover, an attempt has been made to develop a consistent comprehensive interpretation and obtain a correlation between the various results which is obtained experimentally. Identification of a substance is not the end of research but a beginning to go beyond and a person does nothing, if he waited until he could do it so well that no one would find fault with what he has done.